I've absolutely no experience with shooters on the PS3, but since the majority of titles is cross-plattform, I can recommend Call of Duty 4: Modern Warfare. It's looked upon by many for its multiplayer part which is populated by kids mostly, but the single player is an intense and packed experience. It's set in the very near future, too, so it's not sci-fi at all, and it's a few years old already.
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